Inside Cover: Hysteretic Three‐Step Spin Crossover in a Thermo‐ and Photochromic 3D Pillared Hofmann‐type Metal–Organic Framework (Angew. Chem. Int. Ed. 40/2012)
Identifieur interne : 005658 ( Main/Exploration ); précédent : 005657; suivant : 005659Inside Cover: Hysteretic Three‐Step Spin Crossover in a Thermo‐ and Photochromic 3D Pillared Hofmann‐type Metal–Organic Framework (Angew. Chem. Int. Ed. 40/2012)
Auteurs : Natasha F. Sciortino [Australie] ; Katrin R. Scherl-Gruenwald [Australie] ; Guillaume Chastanet [France] ; Gregory J. Halder [États-Unis] ; Karena W. Chapman [États-Unis] ; Jean-François Létard [France] ; Cameron J. Kepert [Australie]Source :
- Angewandte Chemie International Edition [ 1433-7851 ] ; 2012-10-01.
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Abstract
Multistable molecular materials address fundamental questions in the solid state and promise application in a range of molecular devices. In their Communication on page 10154 ff. C. J. Kepert and co‐workers present a metal–organic framework that exhibits a unique hysteretic three‐step spin‐crossover transition. The transition spans four separate lattice spin states and includes two temperature regions over which the material is formally tristable; that is, three of the four states are stable within each of these regions and may be individually accessed through thermal control. (Graphic design by Karl Mutimer.)
Url:
DOI: 10.1002/anie.201207301
Affiliations:
- Australie, France, États-Unis
- Aquitaine, Nouvelle-Aquitaine, Nouvelle-Galles du Sud
- Bordeaux, Sydney
- Université Bordeaux I, Université de Sydney
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In their Communication on page 10154 ff. C. J. Kepert and co‐workers present a metal–organic framework that exhibits a unique hysteretic three‐step spin‐crossover transition. The transition spans four separate lattice spin states and includes two temperature regions over which the material is formally tristable; that is, three of the four states are stable within each of these regions and may be individually accessed through thermal control. 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